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B.Sc.-B.Ed. (Secondary) New (RIE)
Examination, 2025
(Third Semester)
CHEMISTRY-(DC-VI)
(Major)
Organic Chemistry-II
рдиреЛрдЯ : рд╕рднреА рддреАрдиреЛрдВ рдЦрдгреНрдбреЛрдВ рд╕реЗ рдкреНрд░рд╢реНрдиреЛрдВ рдХреЗ рдирд┐рд░реНрджреЗрд╢рд╛рдиреБрд╕рд╛рд░ рдЙрддреНрддрд░ рджреАрдЬрд┐рдП ред рдЕрдВрдХреЛрдВ рдХрд╛ рд╡рд┐рднрд╛рдЬрди рдЦрдгреНрдбреЛрдВ рдХреЗ рд╕рд╛рде рджрд┐рдпрд╛ рдЧрдпрд╛ рд╣реИ ред
Attempt questions of all three Sections as directed.
Distribution of marks is given with Sections.
рдЦрдгреНрдб 'рдЕ'
Section A
(рдЕрддрд┐ рд▓рдШреБ рдЙрддреНрддрд░реАрдп рдкреНрд░рд╢реНрди)
(Very Short Answer Type Questions)
Write elemination reaction with example.
Why are alcohols weaker acids then water ?
How will you synthesis diethyl malonate from acetic acid ?
What are acid anhydrides ? How can they be prepared?
Give Gabriel Phthalimide reaction with example.
рдЦрдгреНрдб 'рдм'
Section B
(рд▓рдШреБ рдЙрддреНрддрд░реАрдп рдкреНрд░рд╢реНрди)
(Short Answer Type Questions)
рдиреЛрдЯ : рд╕рднреА рдкреНрд░рд╢реНрдиреЛрдВ рдХреЗ рдЙрддреНрддрд░ рджреАрдЬрд┐рдП ред рдкреНрд░рддреНрдпреЗрдХ рдкреНрд░рд╢реНрди рдХреЗ рдЕрдВрдХ рд╕рдорд╛рди рд╣реИрдВ ред
Attempt all questions. Each question carries equal marks.
Explain the reaction mechanism of Claisen rearrangements.
What is aldol condensation? Give its reaction mechanism.
What is dehydrohalogenation reaction ? Give reaction mechanism of E2 reaction.
What is Nucleophilic addition-elimination reactions ? Give the reaction mechanism of Cannizzaro reaction.
Write four difference between SN1 and SN2 reaction mechanism.
How will you prepare glycol from ethylene oxide ? Write reaction of Glycol with periodic acid.
How will you prepare lactic acid from Acetylene ? What happens when lactic acid reacts with the following reagents ?
- рдлреЗрдирдЯрди рдЕрднрд┐рдХрд░реНрдордХ (Fenton's reagent)
- рдЖрдпреЛрдбрд┐рди рдФрд░ рдХрд╛рд╕реНрдЯрд┐рдХ рд╕реЛрдбрд╛ (Iodine and caustic soda)
- рд╣рд╛рдЗрдбреНрд░реЛрдмреНрд░реЛрдорд┐рдХ рдЕрдореНрд▓ (Hydrobromic acid)
рдЦрдгреНрдб 'рд╕'
Section C
(рджреАрд░реНрдШ рдЙрддреНрддрд░реАрдп рдкреНрд░рд╢реНрди)
(Long Answer Type Questions)
рдиреЛрдЯ : рд╕рднреА рдкреНрд░рд╢реНрдиреЛрдВ рдХреЗ рдЙрддреНрддрд░ рджреАрдЬрд┐рдП ред рдкреНрд░рддреНрдпреЗрдХ рдкреНрд░рд╢реНрди рдХреЗ рдЕрдВрдХ рд╕рдорд╛рди рд╣реИрдВ ред
Attempt all questions. Each question carries equal marks.
What is Reformatsky's reactions ? Explain its reaction mechanism.
How is Nitrobenzene prepared ? Give the reduction reaction of Nitrobenzene at different medium.
Differentiate between 1┬░, 2┬░ and 3┬░ amines using Hinsberg reagents.
What is organometallic compound ? How is Methyl Magnesium Bromide prepared ? Starting from it prepared the following compound :
- рдПрдереЗрдиреЛрдЗрдХ рдПрд╕рд┐рдб (Ethanoic acid)
- рдПрдереЗрдиреЛрди (Ethanone)
- рдкреНрд░реЛрдкреЗрдиреЛрди (Propanone)
- рдПрдереЗрдиреЙрд▓ (Ethanol)
- рдореАрдереЗрди (Methane)
How will you prepare chlorobenzene from Sadmeyer's reactions ? What happens when Chlorobenzene reacts with following reagents ?
- Mg/рд╢реБрд╖реНрдХ рдИрдерд░ (Mg/Dry ether)
- Ni/Al/NaOH рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ (Ni/Al/NaOH Reaction)
- рдорд┐рдерд╛рдЗрд▓ рдХреНрд▓реЛрд░рд╛рдЗрдб + Na/рд╢реБрд╖реНрдХ рдИрдерд░ (Methyl chloride + Na/dry ether)
- NH3/Cu2O (NH3/Cu2O)
- CuCN/рдкрд┐рд░рд┐рдбреАрди (CuCN/Pyridine)
How is prepared phenol from Grignard reagents ? Starting from phenol prepare the following compounds :
- рдмреЗрдВрдЬреАрди (Benzene)
- P-рд╣рд╛рдЗрдбреНрд░реЙрдХреНрд╕реА рдПрдЬреЛрдмреЗрдВрдЬреАрди (P-Hydroxy azobenzene)
- рдкрд┐рдХреНрд░рд┐рдХ рдПрд╕рд┐рдб (Picric acid)
- рдлрд┐рдиреЙрд▓реНрдлреНрдерд▓реАрди (Phenolphthalein)
- рдмреИрдХреЗрд▓рд╛рдЗрдб (Bakelite)
Explain the preparation, property and structure of ethers.
How will be prepare the following compounds Starting from ethyl acetoacetate :
- рдПрд╕рд┐рдЯрд┐рдХ рдПрд╕рд┐рдб (Acetic acid)
- рд╕рдХреНрд╕рд┐рдирд┐рдХ рдПрд╕рд┐рдб (Succinic acid)
- рдЧреНрд▓реВрдЯрд╛рдорд┐рдХ рдПрд╕рд┐рдб (Glutamic acid)
- рдПрдбрд┐рдкрд┐рдХ рдПрд╕рд┐рдб (Adipic acid)
- рдХреНрд░реЛрдЯреЛрдирд┐рдХ рдПрд╕рд┐рдб (Crotonic acid)
- рд╡реИрд▓реЗрд░рд┐рдХ рдПрд╕рд┐рдб (Valaric acid)
What is carbonyl compound ? What happens when ethanol reacts with the following reagents ?
- рд╣рд╛рдЗрдбреНрд░реЙрдХреНрд╕рд┐рд▓рдПрдорд╛рдЗрди (Hydroxyl amine)
- рд╣рд╛рдЗрдбреНрд░рд╛рдЬреАрди (Hydrazene)
- рдлреЗрд╣рд▓рд┐рдВрдЧ рдШреЛрд▓ (Fehling solution)
- рдЯреЙрд▓реЗрди рдЕрднрд┐рдХрд░реНрдордХ (Tollen reagents)
- рдлреЗрдирд┐рд▓рд╣рд╛рдЗрдбреНрд░рд╛рдЬреАрди (Phenyl hydrazene)
What is Amines ? Give the difference between 1┬║, 2┬║ and tertiary amine on the basis of the following reactions :
- HNO2 рдХреЗ рд╕рд╛рде рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ (Reaction with HNO2)
- CH3COCl рдХреЗ рд╕рд╛рде рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ (Reaction with CH3COCl)
- рдХрд╛рд░реНрдмрд┐рд▓ рдПрдореАрди рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ (Carbyl amine reaction)
- рдорд╕реНрдЯрд░реНрдб рдСрдпрд▓ рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ (Mustard Oil reaction)
- CH3I рдХреЗ рд╕рд╛рде рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ (Reaction with CH3I)
Write short notes on the following :
- ╬▒, ╬▓ рдФрд░ ╬│ рд╣рд╛рдЗрдбреНрд░реЙрдХреНрд╕реА рдЕрдореНрд▓ рдкрд░ рдКрд╖реНрдорд╛ рдХрд╛ рдкреНрд░рднрд╛рд╡ (Effect of heat an ╬▒, ╬▓ and ╬│ hydroxy acid)
- рдХрд░реНрдЯрд┐рдпрд╕ рдкреБрдирд░реНрд╡реНрдпрд╡рд╕реНрдерд╛ рдФрд░ рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ рд╡рд┐рдзрд┐ (Curtius rearrangement and reaction mechanism)
How is prepared Benzene diazonium salt ? Give its four synthesis application.
Write short notes on the following :
- рдПрд╕реНрдЯрд░ рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ рд╡рд┐рдзрд┐ рдХрд╛ рдЕрдореНрд▓реАрдп рд╣рд╛рдЗрдбреНрд░реЛрд▓рд┐рд╕рд┐рд╕ (Acid hydrolysis of ester reactions mechanism)
- рд╣реЙрдлрдореИрди рдмреНрд░реЛрдорд╛рдЗрдб рдЕрдкрдШрдЯрди рдЕрднрд┐рдХреНрд░рд┐рдпрд╛ рдФрд░ рдЙрд╕рдХреА рд╡рд┐рдзрд┐ ред (Hofman bromide degradation reaction and its mechanism.)